Natalia Alexandrovich was born in 1977 in the village of Borki, Mogilev region, Republic of Belarus.

In 1998, she graduated from the Belarus State Economic University (BSEU) and in 2015 she graduated from the Academy of Public Administration under the President of the Republic of Belarus.

After completing her studies at BSEU, she worked at the Economic Office in the Administration of the Leninsky district of Minsk.

2002–2004: Lead Specialist at the Economy Committee of the Minsk City Executive Committee.

In 2004–2011, she worked in the Minsk inspection of the Ministry of Taxes and Duties of the Republic of Belarus occupying various positions: Senior and Chief State Tax Inspector, Deputy Section Head.

2011–2014: Head of the Economic Analysis and Forecasting Office at the Economy Committee of the Minsk City Executive Committee.

Since 2014, she worked at the Ministry of Transport and Communications of the Republic of Belarus where until 2019 she was the Head of the General Directorate of Economy and Finances.

Since April 2019: Deputy Minister of Transport and Communications of the Republic of Belarus.

On October 27, 2025, she was appointed Deputy Director of the Eurasian Economic Commission's Transport and Infrastructure Department.